Organometallic Reagents

Organometallic Reagents : Organic Synthesis

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Organometallic chemistry has always been an important part of organic chemistry, but never more so than today. The expansion of synthetic methodology employing organometallic reagents and metallo-species in the last twenty years has been phenomenal. This book brings together experts across the whole range of fields associated with organometallic chemistry to provide a spectrum of up-to-date information. It will be of interest to organic chemists and medicinal chemists in academia and the pharamceutical industry.
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Product details

  • Hardback | 352 pages
  • 160.3 x 238.5 x 21.1mm | 612.11g
  • Academic Press Inc
  • San Diego, United States
  • English
  • 0124991505
  • 9780124991507

Table of contents

The use of n2Co2(CO)6-Acetylene complexes for the synthesis of enediyne antitumour antibiotics; metals in organic chemistry - is it worth taking the risk?; recent studies on the development of some new organometallic reactions for organic synthesis; stereocontrol in palladium-catalyzed reactions; highly diastereoselective additions of organometallics to chiral 1,3-Oxazolidines; first total synthesis of Scopadulcic Acid B - an illustration of the utility of palladium catalyzed polyene cyclizations; the synthesis of a-heteroalkenylmetals via hydrometallation and metallometallation of alkynes; stereocontrolled, catalytic transitions metal-ene type cyclizations in organic synthesis; perspectives in supramolecular chemistry from molecular recognition towards self-organization; Cram's Rule in radical chemistry; polycycle constructions by transition metal catalyzed and radical mediated processes.
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