Kinetic Peculiarities of Solid Phase Reactions
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Kinetic Peculiarities of Solid Phase Reactions

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Description

Much data has been collected from experiments on the kinetics of radical reactions in different solids. This text should make the experimental data accessible for interested chemists. Looking in detail at the kinetics of solids, the book covers both organic and inorganic materials. This is an introduction to the subject by firstly discussing low-molecular matrices and generalizing the behaviour of polymers, and secondly by examining hydrogen atom transfer, triple carbene reactions and radical pair transformations.
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Product details

  • Hardback | 160 pages
  • 154.94 x 231.14 x 15.24mm | 362.87g
  • John Wiley & Sons Ltd
  • Chichester, United Kingdom
  • English
  • 1. Auflage
  • 0471983748
  • 9780471983743

Back cover copy

Much data has been collected from experiments on the kinetios ofradical reactions in different solids, but to date, this has notbeen presented in book format in a thorough and comprehensive way.This book makes the experimental data accessible for all chemistsinvolved in these reactions. Various models of the tunnel atomtransfer are analyzed in order to explain the kinetic isotopeeffect in solid phase reactions and photoinitiated radicalreactions are inspected for the kinetic non-equivalence ofparticles and factors affecting their reactivity. Topics coveredinclude:
* kinetic description of reactions with dispersion particles inreactivity
* the influence of space-orientation factors on reactivity in cagereactions
* the influence of molecular dynamics on the kinetics of elementaryreactions
* the effect of structural-physical modification on kinetics ofcage radical reactions
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Table of contents

Formally kinetic description of the reactions with dispersions in reactivity; influence of space-orientation factors on reactivity in solids; connection of solid phase kinetics with molecular dynamics; effect of structural-physical modification on kinetics of radical reactions; tunneling in solid phase reactions; kinetic isotope effect in solid phase reactions; kinetics of photoinitiated reactions in solids.
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